uent blood product transfused was red blood cells and the main reasons for transfusion were acute anemia with hemodynamic impact and analytical criteria. Mortality of transfused patients was higher.In order to enhance the catalytic activity of Mn-Ce oxide catalyst for the selective catalytic reduction of NOx with NH3 (NH3-SCR), W was introduced as a promoter. With the doping of W, the NOx conversion over Mn3CeOx catalyst above 150 °C was increased, and the N2O production was significantly decreased. Even in the present of water vapour, Mn3CeW0.3Ox still showed a good SCR activity. https://www.selleckchem.com/products/zasocitinib.html H2-TPR and XPS results suggested that the doping of tungsten could inhibit the charge imbalance and reducibility, which would inhibit NO oxidation to NO2 over Mn3CeOx. As a result, the NOx conversion below 150 °C over Mn3CeW0.3Ox was slightly lower than that over Mn3CeOx. Since the NOx production and the NH3 conversion during the NH3 oxidation of Mn3CeOx were inhibited after the doping of W, the NOx conversion above 150 °C over Mn3CeW0.3Ox was higher than that over Mn3CeOx. The transient reaction demonstrated that the doped W species on Mn3CeW0.3Ox could inhibit the N2O produced by the Langmuir-Hinshelwood mechanism. Kinetic study proved that νSCR over Mn3CeW0.3Ox was obviously higher that over Mn3CeOx, νNSCR and νC-O over Mn3CeOx were much higher than those of Mn3CeW0.3Ox, which were consistent with the SCR activity.Microplastics, as a class of widely dispersed persistent pollutants, the main reactive oxygen species is far from clarified in their photocatalytic degradation. In this study, a novel hydroxy-rich ultrathin BiOCl (BiOCl-X) was prepared at room temperature. BiOCl-X shows a strong potential for photocatalytic degradation of microplastics, and the mass loss of plastics is 24 times higher than that of the BiOCl nanosheets. More importantly, we explored the photocatalytic mechanism through electron paramagnetic resonance and capture experiments, and found that the surface hydroxyl of BiOCl can effectively enhance the production of hydroxyl radicals, resulting in boosting degradation performance. Here, we provide new insights that photocatalytic degradation of microplastic is dependent on surface hydroxyl groups. This work could be useful for controllable designs of hydroxy-rich photocatalysts for applications in microplastic degradation.This study was aimed to prove the effectiveness and practicability of an integrated technology for simultaneous remediation of Cr-contaminated soil and groundwater. The remediation system was built by pumping Cr-contaminated groundwater into top contaminated soil round after round, enabling the pre-applied iron-biochar composite (Fe-BC) in topsoil to stabilize Cr from both groundwater and soil. Immobilization ability and mechanism of Cr in soil were explored by toxicity characteristic leaching procedure test, scanning electron microscopy-elemental mapping, and X-ray photo spectroscopy. Hydrus-1D software was used to examine the long-term stability of immobilized Cr in soil. Results showed that Fe-BC-amended soil could remove about 71% Cr from contaminated groundwater. Meanwhile, Cr from both groundwater and soil was simultaneously immobilized in topsoil, leachability of Cr in which was reduced by over 81%. The immobilization of Cr in soil was attributed to the reduction of Cr(VI) into Cr(III) to form stable CrxFe(1-x)(OH)3. After remediation, the average transport rate of Cr in the soil profile was only 0.420?cm?y-1 along with the local rainfall. Our study demonstrated that integrated technology could effectively remove Cr from groundwater and stabilize Cr in soil and the simultaneous remediation target for both soil and groundwater reached.Low-cost and efficient treatment processes are urgently needed to manage highly decentralized shale gas wastewater, which seriously threatens the environment if not properly treated. We propose a simple integrated pretreatment process for on-site treatment, whereby gravity driven membrane filtration is combined with granular activated carbon (GAC) adsorption and solar aeration. The rationale of exploitment of sustainable solar energy is that most shale gas production areas are decentralized and located in desert/rural areas characterized by relatively scarce transportation and power facilities but also by abundant sunshine. In this study, GAC and aeration significantly increased the stable flux (170%) and improved effluent quality. Specifically, the dissolved organic carbon removal rate of the integrated system was 44.9%. The high stable flux was attributed to a reduction of extracellular polymeric substances accumulated on the membrane, as well as to the more porous and heterogeneous biofilm formed by eukaryotes with stronger active predation behavior. The prevailing strains, Gammaproteobacteria (35.5%) and Alphaproteobacteria (56.5%), played an important active role in organic carbon removal. The integrated system has great potential as pretreatment for shale gas wastewater due to its low energy consumption, low operational costs, high productivity, and effluent quality.Microplastics (MPS) are widespread in our environment and have a potential impact on the reproductive development of humans and mammals. In this study, we evaluated the effect of 5 ?m polystyrene microplastics(PS-MPS) on spermatogenesis in mice. The damage by PS-MPS to epididymal sperm was studied using blood cell counts. The results showed that the number of viable epididymis sperm after PS-MPS exposure was significantly reduced. Using Duff-Quik staining, we found that the PS-MPS exposure increased the rate of sperm deformity. The testis is an important organ responsible for normal spermatogenesis. HE and TUNEL staining showed atrophy, shedding, and apoptosis of sperm cells at all levels of the testis after exposure to PS-MPS. Western blot and qPCR analysis were used to detect Nrf2/HO-1 and NF-κB. The results showed that after PS-MPS exposure, the expression of the pro-inflammatory molecule NF-κB and that of the inflammatory factors interleukin (IL)-1β and IL-6 increased significantly, whereas that of the anti-inflammatory molecule Nrf2/HO-1 decreased.